The effect of acidity and redox capability over sulfuric acid-modified CeO₂ catalysts were studied for the selective catalytic reduction of NO_x with NH₃ (NH₃-SCR). The deposition of sulfate significantly enhanced the catalytic performance over CeO₂. NOx conversion over 4H ₂SO₄/CeO₂ at 230-440 °C was higher than 90%. The strong redox capability of CeO₂ could result in unselective NH₃ oxidation and decrease high temperatures catalytic activity and N₂ selectivity. The deposition of sulfate increased the acidity and weakened the redox capability, and then increased the high temperature NO_x conversion and N₂ selectivity. An appropriate level of acidity also promoted the activity at 190-250 °C over ceria-based catalysts, and with further increase in the acidity, the SCR activity decreased slightly. Weak redox capability lowered the low-temperature catalytic activity. Excellent SCR activity requires a balance of acidity and redox capability on the catalysts.